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umkhiqizo

1,2-epoxybutane(CAS#106-88-7)

Isakhiwo Samakhemikhali:

I-Molecular Formula C4H8O
I-Molar Mass 72.11
Ukuminyana 0.829 g/mL ku-20 °C(lit.)
I-Melting Point -129.28°C
I-Boling Point 63°C(lit.)
I-Flash Point 10°F
Ukuncibilika kwamanzi 86.8g/L ngo-25℃
Ukuncibilika 86.8g/l
I-Vapor Presure 140 mm Hg ( 20 °C)
I-Vapor Density 2.2 (vs air)
Ukubukeka Uketshezi olungenambala olunephunga elimnandi
Umbala Ayinambala kuya Cishe ayinambala
I-BRN 102411
PH 7 (50g/l, H2O, 20℃)
Isimo Sesitoreji Gcina ngaphansi kuka +30°C.
Ukuzinza Izinzile, kodwa ezijwayele ukwenza i-polymerization - isithasiselo singengezwa oketshezini oluhlanzekile. Ivutha kakhulu. Akuhambisani nama-oxidizing ejenti aqinile, ama-asidi, izisekelo, i-anhydrous metal halides, i-amino, i-hydroxyl ne-ca
Umkhawulo Oqhumayo 1.7-19%(V)
I-Refractive Index n20/D 1.384
Izakhiwo Zomzimba Nezamakhemikhali Uketshezi olugelezayo olungenambala. Iphoyinti lokuqandisa -150 ℃, iphoyinti elibilayo 63 ℃, ukuminyana kwesihlobo 0.8312(20/20 ℃), inkomba ye-refractive 1.3840, iphoyinti elikhanyayo -12 ℃. Ixubene nezinyibilikisi eziningi eziphilayo, ezincibilika kancane emanzini.

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi I-R11 – Ivutha Kakhulu
R20/21/22 – Kuyingozi ngokuhogela umoya, ukuthintana nesikhumba futhi uma ukugwinyile.
R36/37/38 – Ukucasula amehlo, uhlelo lokuphefumula kanye nesikhumba.
R40 – Ubufakazi obuncane bomphumela we-carcinogenic
R52/53 – Kuyingozi ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini.
Incazelo Yokuphepha I-S9 – Gcina isiqukathi endaweni enomoya omuhle.
S16 – Zigcine kude nemithombo yokuthungela.
S29 – Ungathululi emiseleni.
I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
I-S61 - Gwema ukudedelwa endaweni. Bheka imiyalelo ekhethekile / amaphepha edatha okuphepha.
S19 -
Ama-ID e-UN UN 3022 3/PG 2
I-WGK Germany 2
I-RTECS EK3675000
I-TSCA Yebo
Ikhodi ye-HS 29109000
I-Hazard Class 3.1
Iqembu Lokupakisha II
Ubuthi I-LD50 ngomlomo kuNogwaja: 500 mg/kg LD50 dermal Rabbit 1743 mg/kg

 

Isingeniso

I-1,2-Epibutane iyinhlanganisela yezinto eziphilayo. Iwuketshezi olungenambala olunephunga elimnandi ekamelweni lokushisa. Okulandelayo yisingeniso sezakhiwo zayo eziyinhloko, ukusetshenziswa, izindlela zokukhiqiza kanye nolwazi lokuphepha:

 

Izakhiwo: Iwuketshezi oluvuthayo olungakha ingxube eqhumayo nomoya-mpilo. Ibuye ibe namandla esikhumbeni esicasulayo kanye ne-eye irritater.

 

Sebenzisa:

I-1,2-Butyloxide isetshenziswa kakhulu ekuhlanganiseni kwe-organic, imithi, izibulala-zinambuzane kanye nezingubo. Kuyinto ephakathi ebalulekile futhi ivame ukusetshenziswa ku-organic synthesis ukulungisa ezinye izinhlanganisela, ezifana notshwala, ama-ketone, ama-ether, njll.

 

Indlela:

I-1,2-Epibutane ingalungiswa ngokusabela kwe-octanol ne-hydrogen peroxide. Indlela eqondile yokulungiselela ukusabela i-octanol nge-hydrogen peroxide phambi kwe-catalyst efanele ukukhiqiza i-1,2-epoxybutane.

 

Ulwazi Lokuphepha:

I-1,2-Epibutane iyinto eyingozi enezingozi ezingaba khona njengokucasuka kanye ne-teratogenicity. Kufanele kuqashelwe ukugwema ukuthinta isikhumba kanye nokuhogela umhwamuko waso ngesikhathi sokusetshenziswa, futhi kufanele kunikezwe izinto zokuzivikela ezifanele njengamagilavu, izibuko, nokuvikela ukuphefumula uma kunesidingo. Ngesikhathi sokugcina nokuphatha, ukunakekelwa kufanele kuthathwe ukuvimbela ukuvutha kanye nogesi omile. Gwema ukuxubana nama-oxidants aqinile nama-asidi ukugwema ukusabela okuyingozi. Lapho kulahlwa udoti, imithetho nemithetho yendawo kufanele ilandelwe.


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