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umkhiqizo

I-3-Nitroaniline(CAS#99-09-2)

Isakhiwo Samakhemikhali:

I-Molecular Formula I-C6H6N2O2
I-Molar Mass 138.12
Ukuminyana 0,901 g/cm3
I-Melting Point 111-114 °C (okhanyisiwe)
I-Boling Point 306 °C
I-Flash Point 196 °C
Ukuncibilika kwamanzi 1.25 g/L
Ukuncibilika 1.25g/l
I-Vapor Presure 1 mm Hg ( 119 °C)
Ukubukeka Amakristalu, I-Crystalline Powder kanye/noma Ama-Chunks
I-Gravity ethize 0.901
Umbala Okuphuzi kuya ku-ocher-ophuzi kuya kuwolintshi
I-Merck 14,6581
I-BRN 636962
pKa 2.466(ku-25℃)
Isimo Sesitoreji Gcina ngaphansi kuka +30°C.
I-Refractive Index 1.6396 (isilinganiso)
Izakhiwo Zomzimba Nezamakhemikhali Ikristalu ephuzi efana nenaliti noma impushana.
indawo encibilikayo 114 ℃
iphoyinti abilayo 286~307 ℃ (ukubola)
ukuminyana kwesihlobo 1.1747
ukuncibilika kuncibilika kancane emanzini, kuncibilika ku-ethanol, ether, methanol.
Sebenzisa Incibilika kancane emanzini, incibilika ku-ethanol, ether, methanol.

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Izimpawu Eziyingozi T – Inobuthi
Amakhodi Engozi R23/24/25 – Kunobuthi ngokuhogela, ukuthintana nesikhumba futhi uma ugwinywe.
I-R33 – Ingozi yemiphumela eqoqwayo
R52/53 – Kuyingozi ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini.
Incazelo Yokuphepha I-S28 – Ngemva kokuxhumana nesikhumba, geza ngokushesha ngensipho eningi.
I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
S45 – Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.)
I-S61 - Gwema ukudedelwa endaweni. Bheka imiyalelo ekhethekile / amaphepha edatha okuphepha.
I-S28A -
Ama-ID e-UN UN 1661 6.1/PG 2
I-WGK Germany 2
I-RTECS BY6825000
AMAKHODI E-FLUKA BRAND F 8
I-TSCA Yebo
Ikhodi ye-HS 29214210
I-Hazard Class 6.1
Iqembu Lokupakisha II
Ubuthi I-Acute LD50 yezingulube ze-Guinea 450 mg/kg, amagundane 308 mg/kg, izigwaca 562 mg/kg, amagundane 535 mg/kg
(ocashuniwe, RTECS, 1985).

 

Isingeniso

I-M-nitroaniline iyinhlanganisela yezinto eziphilayo. Kuyikristalu ephuzi enephunga elibi elingavamile.

 

Ukusetshenziswa okuyinhloko kwe-m-nitroaniline kufana nodayi ophakathi nendawo futhi njengento eluhlaza yeziqhumane. Ingalungisa ezinye izinhlanganisela ngokusabela ngezinhlanganisela ezithile, njengezinhlanganisela ze-nitrate zingalungiswa ngokusabela nge-nitric acid, noma i-dinitrobenzoxazole ingalungiswa ngokusabela nge-thionyl chloride.

 

Indlela yokulungiselela i-m-nitroaniline ingatholwa ngokusabela kwe-m-aminophenol nge-nitric acid. Isinyathelo esiqondile ukuncibilikisa i-m-aminophenol ku-sulfuric acid equkethe i-nitric acid bese ushukumisa ukusabela, bese upholisa futhi ucwebezelise ukuze ekugcineni uthole umkhiqizo we-m-nitroaniline.

 

Ulwazi lokuphepha: I-M-nitroaniline iwubuthi obunomphumela ocasulayo emehlweni, esikhumbeni, nasendleleni yokuphefumula. Ukuthinta isikhumba kungabangela ukuvuvukala nokubabomvu, futhi ukuhogela umhwamuko omningi noma uthuli kungase kubangele ubuthi. Gqoka izibuko zokuzivikela, amagilavu, izingubo zokuzivikela, nama-respirators lapho usebenza, futhi uqinisekise ukuthi ukuhlinza kwenziwa ngaphansi kwezimo ezinomoya omuhle. Noma yikuphi ukuthintana okungenzeka kufanele kugezwe ngokushesha ngamanzi amaningi futhi kuphathwe ngokushesha ngosizo lwezokwelapha. Ngaphezu kwalokho, i-m-nitroaniline iyaqhuma futhi kufanele igcinwe kude namalangabi avulekile kanye namazinga okushisa aphezulu.


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