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umkhiqizo

I-Acrylonitrile(CAS#107-13-1)

Isakhiwo Samakhemikhali:

I-Molecular Formula I-C3H3N
I-Molar Mass 53.06
Ukuminyana 0.806g/mLat 20°C
I-Melting Point -83 °C (ukukhanya)
I-Boling Point 77 °C (okhanyisiwe)
I-Flash Point 32°F
Ukuncibilika kwamanzi Encibilikayo. 7.45 g/100 mL
Ukuncibilika 73g/l
I-Vapor Presure 86 mm Hg ( 20 °C)
I-Vapor Density 1.83 (vs air)
Ukubukeka Uketshezi
Umbala Kucace
Iphunga Iphunga elithambile elifana ne-pyridine ku-2 kuya ku-22 ppm
Umkhawulo Wokuchayeka I-NIOSH REL: TWA 1 ppm, 15-min C 1 ppm, IDLH 85 ppm; OSHAPEL: TWA 2 ppm, 15-min C 10 ppm; I-ACGIH TLV: TWA 2 ppm.
I-Merck 14,131
I-BRN 605310
PH 6.0-7.5 (50g/l, H2O, 20℃)
Isimo Sesitoreji 2-8°C
Kuyazwela Ukukhanya Okuzwelayo
Umkhawulo Oqhumayo 2.8-28%(V)
I-Refractive Index n20/D 1.391(lit.)
Izakhiwo Zomzimba Nezamakhemikhali Ukuminyana Komphunga: 1.83 (vs air)
umfutho womhwamuko: 86 mm Hg (20 ℃)
izimo zokugcina: 2-8℃
ukuzwela: Kuyazwela ukukhanya
I-WGK isiJalimane: 3
I-RTECS:AT5250000

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi R45 – Ingabangela umdlavuza
I-R11 – Ivutha Kakhulu
R23/24/25 – Kunobuthi ngokuhogela, ukuthintana nesikhumba futhi uma ugwinywe.
R37/38 – Ukucasula uhlelo lokuphefumula kanye nesikhumba.
R41 – Ingozi yokulimala okubi emehlweni
R43 - Ingabangela ukuzwela ngokuthinta isikhumba
R51/53 – Ukuba nobuthi ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini.
R39/23/24/25 -
R62 – Ingozi engaba khona yokukhubazeka kokuzala
R63 – Ingozi engaba khona yokulimala enganeni engakazalwa
Incazelo Yokuphepha S53 – Gwema ukuchayeka – thola imiyalelo ekhethekile ngaphambi kokuyisebenzisa.
I-S9 – Gcina isiqukathi endaweni enomoya omuhle.
S16 – Zigcine kude nemithombo yokuthungela.
S45 – Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.)
I-S61 - Gwema ukudedelwa endaweni. Bheka imiyalelo ekhethekile / amaphepha edatha okuphepha.
I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
Ama-ID e-UN UN 1093 3/PG 1
I-WGK Germany 3
I-RTECS AT5250000
AMAKHODI E-FLUKA BRAND F 8
I-TSCA Yebo
Ikhodi ye-HS 29261000
I-Hazard Class 3
Iqembu Lokupakisha I
Ubuthi I-LD50 yomlomo kumagundane: 0.093 g/kg (Smyth, Carpenter)

 

Isingeniso

I-Acrylontril iwuketshezi olungenambala olunephunga elimnandi. Inephuzu eliphansi lokubilisa kanye nephuzu eliphazimayo eliphakeme, kulula ukuvungama. I-Acrylontril ayincibiliki emanzini ezingeni lokushisa elivamile, kodwa incibilika kuzincibilikisi eziningi eziphilayo.

 

I-acrylontrile inezinhlobonhlobo zezicelo. Okokuqala, kuyimpahla ebalulekile yokwakhiwa kwemicu yokwenziwa, kanye nokwakhiwa kwenjoloba, amapulasitiki kanye nezingubo. Okwesibili, i-acrylontrile ingasetshenziswa futhi ekwenzeni amafutha athosiwe anephunga elimnandi, izithasiselo zikaphethiloli, imikhiqizo yokunakekelwa kwezinwele, odayi kanye nemithi ephakathi kwemithi. Ngaphezu kwalokho, i-acrylontril ingasetshenziswa futhi njenge-solvent, i-extractant kanye ne-catalyst yokusabela kwe-polymerization.

 

i-acrylontril ingalungiswa ngokusabela kwamakhemikhali okubizwa ngokuthi i-cyanidation. Le nqubo ivame ukwenziwa ngokuphendula i-propylene ne-sodium cyanide phambi kwe-ammonia egayiwe ukuze kukhiqizwe i-acrylontril.

 

Udinga ukunaka ukuphepha kwayo lapho usebenzisa i-acrylontril. I-acrylnitril ivutha kakhulu, ngakho-ke kuyadingeka ukugwema ukuchayeka emalangabi avulekile namazinga okushisa aphezulu. Ngenxa yemvelo yayo enobuthi obuphezulu, abaqhubi kufanele bagqoke izinto zokuzivikela ezifana nezibuko namagilavu. Ukuchayeka ku-acrylontril isikhathi eside noma ekugxiliseni okuphezulu kungabangela izinkinga zempilo ezifana nokucasuka kwesikhumba, ubuhlungu bamehlo, nobunzima bokuphefumula. Ngakho-ke, kuyadingeka ukuqinisekisa ukungena komoya okuhle uma usebenzisa, futhi unake ukulandela izinqubo zokusebenza ezifanele kanye nemihlahlandlela yokusebenza ephephile. Uma ukuthintana noma ukuhogela i-acrylitril kubangela ukungakhululeki, funa usizo lwezokwelapha ngokushesha.


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