isibhengezo_sekhasi

umkhiqizo

i-cyclopentadiene(CAS#542-92-7)

Isakhiwo Samakhemikhali:

I-Molecular Formula C5H6
I-Molar Mass 66.1
Ukuminyana d40 0.8235; d410 0.8131; d420 0.8021; d425 0.7966; d430 0.7914
I-Melting Point -85°; mp32.5°
I-Boling Point bp760 41.5-42.0°
Ukuncibilika kwamanzi 10.3 mM ku-25 °C (shake flask-UV spectrophotometry, Streitwieser and Nebenzahl, 1976)
Ukuncibilika Ihlangana ne-acetone, benzene, carbon tetrachloride, ne-ether. Incibilika ku-acetic acid, i-aniline, ne-carbon disulfide (Windholz et al., 1983).
I-Vapor Presure 381 ku-20.6 °C, 735 ku-40.6 °C, 1,380 ku-60.9 °C (Stoeck noRoscher, 1977)
Ukubukeka Uketshezi olungenambala
Umkhawulo Wokuchayeka I-TLV-TWA 75 ppm (~202 mg/m3) (ACGIH,NIOSH, ne-OSHA); IDLH 2000 ppm(NIOSH).
pKa 16(ku-25℃)
Ukuzinza Izinzile ezingeni lokushisa legumbi. Akuhambisani nama-oxidizing agents, ama-acids kanye nezinhlobonhlobo zezinye izinhlanganisela. Ingakha ama-peroxides endaweni yokugcina. Ingase yenzeke ngokuzenzakalelayo i-polymerisation.Ibola lapho ishisa
I-Refractive Index nD16 1.44632
Izakhiwo Zomzimba Nezamakhemikhali Lo mkhiqizo uwuketshezi olungenambala, i-MP-97.2 ℃, BP 40 ℃,n20D 1.4446, ukuminyana okuhlobene 0.805 (19/4 ℃), oxubeka notshwala, i-ether, i-carbon tetrachloride, encibilika ku-carbon disulfide, i-aniline ne-acetic acid. upharafini owuketshezi, ongancibiliki emanzini. I-polymerization yenziwa ekamelweni lokushisa ukukhiqiza i-dicyclopentadiene. cyclopentadiene dimer, MP -1 ℃, BP 170 ℃,n20D 1.1510, ukuminyana kwesihlobo 0.986. I-Cyclopentadiene ngokuvamile ikhona njenge-dimer.

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Ama-ID e-UN 1993
I-Hazard Class 3.2
Iqembu Lokupakisha III
Ubuthi I-LD50 ye-dimer ngomlomo kumagundane: 0.82 g/kg (Smyth)

 

Isingeniso

I-Cyclopentadiene (C5H8) iwuketshezi olungenambala, olunephunga elimnandi. I-olefin engazinzile kakhulu eyenziwe nge-polymerized futhi icishe ivuthe.

 

I-Cyclopentadiene inezinhlobonhlobo zezicelo ocwaningweni lwamakhemikhali. Ingasetshenziswa futhi njengento eluhlaza yama-polymers nama-rubber ukuthuthukisa izakhiwo zabo zomzimba namakhemikhali.

 

Kunezindlela ezimbili eziyinhloko zokulungiselela i-cyclopentadiene: eyodwa ikhiqizwa ngokuqhekeka kwamafutha kapharafini, kanti enye ilungiswa ukusabela kwe-isomerization noma ukusabela kwe-hydrogenation kwe-olefins.

 

I-Cyclopentadiene iguquguquka kakhulu futhi iyavutha, futhi iwuketshezi oluvuthayo. Enqubweni yokugcina nokuthutha, izinyathelo zokuvimbela umlilo nokuqhuma kufanele zithathwe ukuze kugwenywe ukuthintana namalangabi avulekile kanye namazinga okushisa aphezulu. Gqoka okokuvikela okufanele okufana namagilavu, izibuko, nezingubo eziqhumayo lapho usebenzisa futhi uphethe i-cyclopentadiene. Ngesikhathi esifanayo, ukunakekelwa kufanele kuthathwe ukuze ugweme ukuthintana nesikhumba kanye ne-inhalation ye-vapor yayo, ukuze ungabangeli ukucasuka kanye nobuthi. Esimeni lapho kuvuza ngengozi, nqamula umthombo wokuvuza ngokushesha futhi uwuhlanze ngezinto ezifanele zokumunca. Emkhiqizweni wezimboni, izinqubo zokuphepha ezifanele kanye nezinyathelo kufanele zilandelwe ukuze kuqinisekiswe ukuphepha kokusebenza.


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