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umkhiqizo

I-Lithium borohydride(CAS#16949-15-8)

Isakhiwo Samakhemikhali:

I-Molecular Formula BH4Li
I-Molar Mass 21.78
Ukuminyana 0.896g/mLat 25°C
I-Melting Point 280 °C
I-Boling Point 66°C/760mmHg
I-Flash Point −1°F
Ukuncibilika kwamanzi I-H2O encibilikayo ngaphezu kwe-pH 7, i-ether, i-tetrahydrofuran, i-aliphatic amines [MER06]
Ukuncibilika Incibilika ku-ether, THF, nama-aliphatic aminesIncibilika ku-ether, tetrahydrofuran, aliphatic amines ne-ethanol.
Ukubukeka Impushana
I-Gravity ethize 0.66
Umbala Emhlophe
I-Merck 14,5525
Isimo Sesitoreji indawo engenamanzi
Kuyazwela Kuyazwela Umoya Nomswakama
Umkhawulo Oqhumayo 4.00-75.60%(V)

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi R14/15 -
R23/24/25 – Kunobuthi ngokuhogela, ukuthintana nesikhumba futhi uma ugwinywe.
R34 – Ibangela ukusha
R20/21/22 – Kuyingozi ngokuhogela umoya, ukuthintana nesikhumba futhi uma ukugwinyile.
I-R11 – Ivutha Kakhulu
R40 – Ubufakazi obuncane bomphumela we-carcinogenic
R36/37/38 – Ukucasula amehlo, uhlelo lokuphefumula kanye nesikhumba.
I-R19 – Ingase yenze ama-peroxides aqhumayo
R67 – Izihwamuko zingadala ukozela kanye nesiyezi
R66 – Ukuchayeka kaningi kungabangela ukomisa kwesikhumba noma ukuqhekeka
I-R22 – Iyingozi uma igwinywe
I-R12 – Ivutha Kakhulu
Incazelo Yokuphepha S26 – Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha.
S36/37/39 – Gqoka izingubo zokuzivikela ezifanele, amagilavu ​​kanye nokuvikela iso/ubuso.
S43 – Uma kusetshenziswa umlilo … (kulandela uhlobo lwempahla yokucisha umlilo ezosetshenziswa.)
S45 – Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.)
I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
S16 – Zigcine kude nemithombo yokuthungela.
Ama-ID e-UN UN 3399 4.3/PG 1
I-WGK Germany 2
I-RTECS ED2725000
AMAKHODI E-FLUKA BRAND F 10-21
I-TSCA Yebo
Ikhodi ye-HS 2850 00 20
I-Hazard Class 4.3
Iqembu Lokupakisha I

 

Isingeniso

I-Lithium borohydride iyinhlanganisela ye-inorganic ne-chemical formula BH4Li. Kuyinto eqinile, ngokuvamile ngesimo se-white crystalline powder. I-Lithium borohydride inezici ezilandelayo:

 

1. Umthamo omkhulu wokugcina i-hydrogen: I-Lithium borohydride iyinto enhle kakhulu yokugcina i-hydrogen, engagcina i-hydrogen ngesilinganiso esikhulu sesisindo.

 

2. Ukunyibilika: I-Lithium borohydride inokunyibilika okuphezulu futhi ingancibilika kuzincibilikisi eziningi eziphilayo, njenge-ether, i-ethanol ne-THF.

 

3. Ukuvutha okuphezulu: I-Lithium borohydride ingashiswa emoyeni futhi ikhulule inani elikhulu lamandla.

 

Ukusetshenziswa okuyinhloko kwe-lithium borohydride yilezi:

 

1. Isitoreji se-hydrogen: Ngenxa yomthamo wayo omkhulu wokugcina i-hydrogen, i-lithium borohydride isetshenziswa kabanzi emkhakheni wamandla e-hydrogen ukugcina nokukhulula i-hydrogen.

 

2. Ukwenziwa kwe-Organic: I-Lithium borohydride ingasetshenziswa njenge-ejenti enciphisa ukusabela kwe-hydrogenation ekuphenduleni kwe-organic chemical synthesis.

 

3. Ubuchwepheshe bebhethri: I-Lithium borohydride ingasetshenziswa futhi njengesengezo se-electrolyte kumabhethri e-lithium-ion.

 

Indlela yokulungiselela i-lithium borohydride ngokuvamile ilungiswa ngokusabela kwe-lithium metal ne-boron trichloride. Indlela eqondile yokulungiselela imi kanje:

 

1. Ukusebenzisa i-ether anhydrous njenge-solvent, insimbi ye-lithium yengezwa ku-ether endaweni engasebenzi.

 

2. Engeza isisombululo se-ether se-boron trichloride ensimbi ye-lithium.

 

3. Ukusabela okushisa okushukumisayo nokuqhubekayo kuyenziwa, futhi i-lithium borohydride ihlungwa ngemva kokuba ukusabela kuqediwe.

 

1. I-Lithium borohydride kulula ukuyishisa lapho ithintana nomoya, ngakho gwema ukuthintana namalangabi avulekile kanye nezinto ezishisa kakhulu.

 

2. I-Lithium borohydride iyacasula esikhumbeni nasemahlweni, futhi izinto zokuzivikela ezifanele ezifana namagilavu ​​nezibuko kufanele zigqokwe lapho usebenza.

 

3. I-Lithium borohydride kufanele igcinwe endaweni eyomile, kude namanzi kanye nendawo eswakeme, ukuyivimbela ekumunceni umswakama futhi ibole.

 

Sicela uqinisekise ukuthi uziqondile futhi wazi kahle izindlela zokusebenza nolwazi lokuphepha ngaphambi kokusebenzisa i-lithium borohydride. Uma ungaphephile noma ungabaza, kufanele ufune isiqondiso sochwepheshe.


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