isibhengezo_sekhasi

umkhiqizo

I-Nitrobenzene(CAS#98-95-3)

Isakhiwo Samakhemikhali:

I-Molecular Formula I-C6H5NO2
I-Molar Mass 123.11
Ukuminyana 1.196 g/mL ku-25 °C (okhanyisiwe)
I-Melting Point 5-6 °C (okhanyisiwe)
I-Boling Point 210-211 °C (okhanyisiwe)
I-Flash Point 190°F
Ukuncibilika kwamanzi encibilikayo kancane
Ukuncibilika 1.90g/l
I-Vapor Presure 0.15 mm Hg ( 20 °C)
I-Vapor Density 4.2 (vs air)
Ukubukeka Uketshezi
Umbala Okuphuzi okucacile
Umkhawulo Wokuchayeka I-TLV-TWA 1 ppm (~5 mg/m3) (ACGIH,MSHA, ne-OSHA); IDLH 200 ppm(NIOSH).
I-Merck 14,6588
I-BRN 507540
pKa 3.98(ku-0℃)
PH 8.1 (1g/l, H2O, 20℃)
Isimo Sesitoreji Gcina ngaphansi kuka +30°C.
Ukuzinza Izinzile. Akuhambisani nama-oxidizing agents aqinile, ama-ejenti anciphisa amandla, izisekelo eziqinile. Okuvutha umlilo. Qaphela imikhawulo yokuqhuma okubanzi.
Umkhawulo Oqhumayo 1.8-40%(V)
I-Refractive Index n20/D 1.551(lit.)
Izakhiwo Zomzimba Nezamakhemikhali Umkhiqizo omsulwa awunambala ukuya kuketshezi olunamafutha aphuzi okhanyayo.
iphoyinti elincibilikayo 5.85 ℃
iphoyinti abilayo 210.9 ℃
ukuminyana kwesihlobo 1.2037
inkomba ye-refractive 1.55296
iphoyinti elikhanyayo 88 ℃
I-soluble ku-ethanol, i-ether ne-benzene, inyibilika kancane emanzini.
Umkhiqizo ohlanzekile uwuketshezi olunamafutha angenambala kuya kokuphuzi okuphaphathekile. Incibilika ku-ethanol, i-ether ne-benzene, inyibilika emanzini.
Sebenzisa I-nitrobenzene iyingxenye ebalulekile yemvelo yayo. I-nitrobenzene yenziwa i-sulfonated ne-sulphur trioxide ukuze kutholwe i-m-nitrobenzene sulfonic acid. Ingasetshenziswa njengodayi ophakathi nendawo, i-oxidant emnene kanye nosawoti ophikisana nodayi. I-nitrobenzene yayixutshwe ne-chlorosulfonic acid ukuze kutholwe i-m-nitrobenzenesulfonyl chloride, eyayisetshenziswa njengendawo emaphakathi yodayi, umuthi nokunye. I-nitrobenzene ifakwe i-chlorine ku-M-nitrochlorobenzene, esetshenziswa kakhulu ekukhiqizeni odayi nezibulala-zinambuzane. Ngemuva kokunciphisa, i-M-chloroaniline ingatholakala. Isetshenziswa njengodayi owolintshi iGC, futhi iyikhemisi, isibulala-zinambuzane, i-fluorescent whitening agent, i-organic pigment intermediates. I-nitrobenzene re-nitration ingaba i-m-dinitrobenzene, ngokuncishiswa ingaba i-m-phenylenediamine, isetshenziswe njengeziphakathi zikadayi, i-epoxy resin yokwelapha i-epoxy resin, izithasiselo ze-petroleum, i-Cement accelerator, i-M-dinitrobenzene efana ne-sodium sulfide ngokwengxenye futhi isimiso ku-M-nitroaniline. Ngokwesisekelo sikadayi osawolintshi R, udayi we-azo ophakathi nendawo kanye nombala wemvelo.

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi R23/24/25 – Kunobuthi ngokuhogela, ukuthintana nesikhumba futhi uma ugwinywe.
R40 – Ubufakazi obuncane bomphumela we-carcinogenic
R48/23/24 -
R51/53 – Ukuba nobuthi ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini.
R62 – Ingozi engaba khona yokukhubazeka kokuzala
R39/23/24/25 -
I-R11 – Ivutha Kakhulu
R36/37/38 – Ukucasula amehlo, uhlelo lokuphefumula kanye nesikhumba.
I-R60 - Ingase iphazamise inzalo
R52/53 – Kuyingozi ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini.
R48/23/24/25 -
R36 – Ukucasuka emehlweni
R20/21/22 – Kuyingozi ngokuhogela umoya, ukuthintana nesikhumba futhi uma ukugwinyile.
Incazelo Yokuphepha I-S28 – Ngemva kokuxhumana nesikhumba, geza ngokushesha ngensipho eningi.
I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
S45 – Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.)
I-S61 - Gwema ukudedelwa endaweni. Bheka imiyalelo ekhethekile / amaphepha edatha okuphepha.
I-S28A -
S16 – Zigcine kude nemithombo yokuthungela.
I-S7 – Gcina isitsha sivalwe ngokuqinile.
S27 – Khumula ngokushesha zonke izingubo ezingcolile.
S53 – Gwema ukuchayeka – thola imiyalelo ekhethekile ngaphambi kokuyisebenzisa.
S26 – Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha.
Ama-ID e-UN UN 1662 6.1/PG 2
I-WGK Germany 2
I-RTECS DA6475000
I-TSCA Yebo
Ikhodi ye-HS 29042010
I-Hazard Class 6.1
Iqembu Lokupakisha II
Ubuthi I-LD50 ngomlomo kumagundane: 600 mg/kg (PB91-108398)

 

Isingeniso

I-Nitrobenzene) ingxube yemvelo engaba ikristale eqinile emhlophe noma uketshezi oluphuzi olunephunga elikhethekile. Okulandelayo yisingeniso kwezinye zezakhiwo, ukusetshenziswa, izindlela zokulungisa kanye nolwazi lokuphepha lwe-nitrobenzene:

 

Ikhwalithi:

I-nitrobenzene ayincibiliki emanzini kodwa iyancibilika kuzincibilikisi zemvelo ezifana notshwala nama-ether.

Ingatholwa nge-nitrate benzene, ekhiqizwa ngokusabela kwe-benzene nge-nitric acid egxilile.

I-Nitrobenzene iyinhlanganisela ezinzile, kodwa futhi iyaqhuma futhi inokuvutha okuphezulu.

 

Sebenzisa:

I-Nitrobenzene iyikhemikhali ebalulekile yempahla eluhlaza futhi isetshenziswa kakhulu ku-organic synthesis.

I-nitrobenzene ingasetshenziswa futhi njengesengezo kuzincibilikisi, amapende kanye nama-coatings.

 

Indlela:

Indlela yokulungisa i-nitrobenzene itholakala ikakhulukazi ngokusabela kwe-nitrification ye-benzene. Elabhorethri, i-benzene ingaxutshwa ne-nitric acid egxilile kanye ne-concentrated sulfuric acid, inyakaziswa emazingeni okushisa aphansi, bese ihlanjululwa ngamanzi abandayo ukuze kutholakale i-nitrobenzene.

 

Ulwazi Lokuphepha:

I-nitrobenzene iyinhlanganisela enobuthi, futhi ukuchayeka noma ukuhogela umhwamuko wayo kungabangela umonakalo emzimbeni.

Kuyinhlanganisela evuthayo futhi eqhumayo futhi kufanele igweme ukuthintana nemithombo yokuthungela.

Izinto zokuzivikela ezifana namagilavu ​​okuzivikela kanye nezibuko kufanele zigqokwe lapho uphatha i-nitrobenzene, futhi indawo yokusebenza enomoya omuhle kufanele inakekelwe.

Uma kwenzeka kuvuza noma ingozi, izinyathelo ezifanele kufanele zithathwe ngokushesha ukuze kuhlanzwe futhi kulahle. Ukuthobela imithetho efanele kanye nemithethonqubo yokulahla kahle imfucuza edaliwe.


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