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umkhiqizo

I-Pentaerythritol CAS 115-77-5

Isakhiwo Samakhemikhali:

I-Molecular Formula I-C5H12O4
I-Molar Mass 136.15
Ukuminyana 1.396
I-Melting Point 253-258 °C (okhanyisiwe)
I-Boling Point 276 °C/30 mmHg (okhanyisiwe)
I-Flash Point 240 °C
Ukuncibilika kwamanzi 1 g/18 mL (15 ºC)
Ukuncibilika I-H2O: 0.1g/mL, icacile, ayinambala
I-Vapor Presure <1 mm Hg ( 20 °C)
Ukubukeka Amakristalu
Umbala Emhlophe
Umkhawulo Wokuchayeka ACGIH: TWA 10 mg/m3OSHA: TWA 15 mg/m3; TWA 5 mg/m3NIOSH: TWA 10 mg/m3; TWA 5 mg/m3
I-Merck 14,7111
I-BRN 1679274
pKa 13.55±0.10(Okubikezelwe)
PH 3.5-4.5 (100g/l, H2O, 35℃)
Isimo Sesitoreji Gcina ngaphansi kuka +30°C.
Ukuzinza Izinzile. Akuhambisani nama-acids aqinile, ama-oxidizing aqinile, ama-acid chloride, ama-anhydrides ane-asidi. Okuvuthayo.
Kuyazwela I-Hygroscopic
I-Refractive Index 1.548
Izakhiwo Zomzimba Nezamakhemikhali Ikristalu yempushana emhlophe enohlamvu.
Indawo encibilikayo: 261 ~ 262 ℃
Indawo yokubilisa: 276 ℃
ukuminyana okuhlobene: 1.395g/cm3
inkomba ye-refractive: 1.548
lapho ukuncibilika kungu-15 ℃, i-1g ichithwa ku-18ml wamanzi. Incibilika ku-ethanol, glycerol, ethylene glycol, formamide. Ayincibiliki ku-acetone, benzene, carbon tetrachloride, ether kanye ne-petroleum ether.
Sebenzisa Isetshenziswa embonini yokumboza, ingasetshenziswa futhi ukulungisa Aviation Lubricants, iziqhumane, ama-plasticizers, ama-stabilizers.

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi 33 - Ingozi yemiphumela eqoqwayo
Incazelo Yokuphepha 24/25 - Gwema ukuthintana nesikhumba namehlo.
I-WGK Germany 1
I-RTECS RZ2490000
I-TSCA Yebo
Ikhodi ye-HS 29054200
Ubuthi I-LD50 ngomlomo kuNogwaja: > 5110 mg/kg LD50 dermal Rabbit > 10000 mg/kg

 

Isingeniso

I-2,2-Bis(hydroxymethyl)1,3-propanediol, eyaziwa nangokuthi i-TMP noma i-trimethylalkyl triol, iyinhlanganisela yezinto eziphilayo. Okulandelayo yisingeniso sezakhiwo zayo, ukusetshenziswa kwayo, izindlela zokukhiqiza kanye nolwazi lokuphepha:

 

Ikhwalithi:

- Ukubukeka: I-2,2-Bis(hydroxymethyl)1,3-propanediol iwuketshezi lwe-viscous olungenambala ukuya kokuphuzi.

- I-Solubility: Incibilika emanzini kanye nenhlobonhlobo yezincibilikisi eziphilayo njenge-ethers, i-alcohol, nama-ketones.

- Ukuzinza: Azinzile ngaphansi kwezimo ezivamile ze-oxidation, kodwa izobola ngaphansi kwezimo zokushisa eziphezulu kanye nezimo ezine-asidi.

 

Sebenzisa:

- Isisekelo sento: 2,2-bis(hydroxymethyl)1,3-propanediol iyikhemikhali ephakathi nendawo futhi eyisisekelo, engasetshenziswa ukuhlanganisa ezinye izinhlanganisela eziphilayo.

- I-flame retardant: Ingasetshenziswa njenge-flame retardant ekuhlanganiseni kwezinto ze-polyurea polymer kanye ne-polymer coatings.

- Ukulungiswa kwama-ester compounds: I-2,2-Bis (i-hydroxymethyl) i-1,3-propanediol ingasetshenziswa ukulungisa ama-ester compounds, njenge-polyester polyester kanye ne-polyester polymers.

 

Indlela:

- Ingalungiselelwa ukusabela kwe-condensation kwe-formaldehyde ne-methanol: okokuqala, i-formaldehyde ne-methanol isabela nge-methanol ngaphansi kwezimo ze-alkaline ukwakha i-methanol hydroxyformaldehyde, bese i-2,2-bis (hydroxymethyl) i-1,3-propanediol yakhiwa ukusabela kwe-condensation kwama-bimolecules ne-methanol ngaphansi kwezimo ezine-acidic.

 

Ulwazi Lokuphepha:

I-2,2-Bis(hydroxymethyl)1,3-propanediol ngokuvamile iphephile ngaphansi kwezimo ezivamile zokusetshenziswa, kodwa okulandelayo kufanele kuqashelwe:

- Ingase ibe ukungcola: I-2,2-bis(hydroxymethyl)1,3-propanediol etholakala ngokwentengiso ingase iqukathe amanani amancane okungcola noma ukungcola, ngakho qaphela ukuhlola ilebula futhi uthenge imikhiqizo kubahlinzeki abathembekile uma uyisebenzisa.

- Ukucasuka kwesikhumba: Kungase kube nomthelela ocasulayo esikhumbeni nasemehlweni, futhi kufanele kuthathwe izinyathelo zokuphepha ezidingekayo lapho uthintwa, njengokugqoka amagilavu ​​amakhemikhali kanye nezibuko, nokugwema ukuthintana ngqo.

- Izimo zesitoreji: Inhlanganisela kufanele igcinwe endaweni emnyama, eyomile futhi enomoya omuhle, kude nomlilo, amazinga okushisa aphezulu, kanye nama-oxidants.

- Ubuthi: I-2,2-Bis(hydroxymethyl)1,3-propanediol inobuthi obuncane, kodwa kusafanele igwenywe ukuze imunce noma ihogele.


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