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umkhiqizo

I-Potassium borohydride(CAS#13762-51-1)

Isakhiwo Samakhemikhali:

I-Molecular Formula BH4K
I-Molar Mass 53.94
Ukuminyana 1.18 g/mL ku-25 °C (lit.)
I-Melting Point 500 °C (dec.) (ekhanyayo)
Ukuncibilika kwamanzi 190 g/L (25 ºC)
Ukubukeka Impushana
I-Gravity ethize 1.178
Umbala Emhlophe
I-Merck 14,7616
Isimo Sesitoreji indawo engenamanzi
Kuyazwela Kuyazwela umswakama
I-Refractive Index 1.494
Izakhiwo Zomzimba Nezamakhemikhali Amakristalu amhlophe noma i-crystalline powder kancane empunga-ophuzi. Ukuminyana 1.178g/cm3. I-hygroscopic kancane emoyeni, ayizinzile. Chaza emanzini, kancane kancane ukhulule i-hydrogen. Incibilika ku-ammonia ewuketshezi, ama-amine, i-methanol-encibilikayo, i-ethanol, ayincibiliki ku-ether, benzene, Tetrahydrofuran, methyl ether namanye ama-hydrocarbon. Ingabola nge-asidi ukuze ikhulule i-hydrogen. Izinzile esisekelweni. Ukubola cishe ku-500 °c ku-vacuum.
Sebenzisa Isetshenziswa njenge-ejenti yokunciphisa ama-aldehydes, ama-ketones nama-acid chlorides, njll. Isetshenziswa njenge-ejenti yokunciphisa i-Analytical Chemistry, izibulala-zinambuzane, imboni yamaphepha kanye neminye imikhiqizo emihle yamakhemikhali, futhi ingasetshenziselwa ukwelashwa kwe-mercury-containing. amanzi angcolile, njll.

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi R14/15 -
R24/25 -
R34 – Ibangela ukusha
I-R11 – Ivutha Kakhulu
Incazelo Yokuphepha S26 – Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha.
S36/37/39 – Gqoka izingubo zokuzivikela ezifanele, amagilavu ​​kanye nokuvikela iso/ubuso.
S43 – Uma kusetshenziswa umlilo … (kulandela uhlobo lwempahla yokucisha umlilo ezosetshenziswa.)
S45 – Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.)
I-S7/8 -
I-S28A -
S16 – Zigcine kude nemithombo yokuthungela.
Ama-ID e-UN UN 1870 4.3/PG 1
I-WGK Germany -
I-RTECS TS7525000
AMAKHODI E-FLUKA BRAND F 10
I-TSCA Yebo
Ikhodi ye-HS 2850 00 20
I-Hazard Class 4.3
Iqembu Lokupakisha I
Ubuthi I-LD50 ngomlomo kuNogwaja: 167 mg/kg LD50 dermal Rabbit 230 mg/kg

 

Isingeniso

I-Potassium borohydride iyinhlanganisela ye-inorganic. Izici zayo zimi kanje:

 

1. Ukubukeka: I-Potassium borohydride iyimpushana yekristalu emhlophe noma i-granule.

 

3. Ukunyibilika: I-Potassium borohydride iyancibilika emanzini futhi kancane kancane i-hydrolyzed emanzini ukuze ikhiqize i-hydrogen ne-potassium hydroxide.

 

4. Amandla adonsela phansi athile: Ukuminyana kwe-potassium borohydride cishe ku-1.1 g/cm³.

 

5. Ukuzinza: Ngaphansi kwezimo ezivamile, i-potassium borohydride izinzile, kodwa ingase ibole lapho kukhona izinga lokushisa eliphezulu, umswakama ophezulu kanye nama-oxidants aqinile.

 

Ukusetshenziswa okuyinhloko kwe-potassium borohydride kuhlanganisa:

 

1. Umthombo we-Hydrogen: I-Potassium borohydride ingasetshenziswa njenge-reagent yokuhlanganiswa kwe-hydrogen, ekhiqizwa ngokuphendula ngamanzi.

 

2. I-ejenti yokunciphisa amakhemikhali: I-borohydride ye-potassium inganciphisa izinhlobonhlobo zezinhlanganisela ezihambisanayo ezifana ne-alcohols, aldehydes, nama-ketones.

 

3. Ukwelashwa kwensimbi yensimbi: I-Potassium borohydride ingasetshenziselwa ukwelashwa kwe-electrolytic hydrogenation yezindawo zensimbi ukunciphisa ama-oxide angaphezulu.

 

Izindlela zokulungiselela ze-potassium borohydride ikakhulukazi zihlanganisa indlela yokunciphisa ngokuqondile, indlela ye-antiborate kanye nendlela yokunciphisa i-aluminium powder. Phakathi kwazo, indlela evame ukusetshenziswa kakhulu itholakala ngokusabela kwe-sodium phenylborate ne-hydrogen ngaphansi kwesenzo se-catalyst.

 

Imininingwane yokuphepha ye-potassium borohydride imi kanje:

 

1. I-Potassium borohydride inokuncibilika okuqinile, futhi i-hydrogen ikhiqizwa lapho ihlangana namanzi ne-asidi, ngakho idinga ukusebenza endaweni enomoya omuhle.

 

2. Gwema ukuthinta isikhumba, amehlo, nemigudu yokuphefumula ukuze uvimbele ukucasuka nokulimala.

 

3. Lapho ugcina futhi usebenzisa i-potassium borohydride, kufanele kuqashelwe ukuvimbela ukuthintana nama-oxidants nezinye izinto ukuvimbela umlilo noma ukuqhuma.

 

4. Ungaxubi i-potassium borohydride nezinto ezine-asidi ukuze ugweme ukwakheka kwamagesi ayingozi.

 

5. Lapho kulahlwa udoti we-potassium borohydride, kufanele kulandelwe imithetho efanele yezemvelo nezokuphepha.


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