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umkhiqizo

I-Propargyl bromide(CAS#106-96-7)

Isakhiwo Samakhemikhali:

I-Molecular Formula I-C3H3Br
I-Molar Mass 118.96
Ukuminyana 1.38g/mLat 20°C
I-Melting Point -61°C
I-Boling Point 97°C
I-Flash Point 65°F
Ukuncibilika kwamanzi Ihlangana ne-ethanol, i-ether, i-benzene, i-carbon tetrachloride ne-chloroform. Akuhambisani namanzi.
I-Vapor Presure 64.6mmHg ku-25°C
Ukubukeka Uketshezi
Umbala Okungenambala - Ophuzi
Umkhawulo Wokuchayeka ACGIH: TWA 20 ppmOSHA: Ceiling 300 ppm; TWA 200 ppmNIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); I-STEL 150 ppm(560 mg/m3)
I-BRN 605309
Isimo Sesitoreji 2-8°C
Kuyazwela Ukukhanya Okuzwelayo
I-Refractive Index n20/D 1.494
Izakhiwo Zomzimba Nezamakhemikhali uketshezi olukhanyayo oluphuzi olunobuthi obukhulu.
indawo yokubilisa 80~90 ℃
ukuminyana 1.335
inkomba ye-refractive 1.4940
iphoyinti elikhanyayo 10 ℃
Incibilika ku-ethanol, ether, benzene ne-chloroform.
Sebenzisa Okwe-Organic synthesis

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi I-R60 - Ingase iphazamise inzalo
U-R61 - Ingabangela ukulimala enganeni engakazalwa
R20/21 – Kuyingozi ngokuhogela umoya nangokuthinta isikhumba.
R25 – Kunobuthi uma ugwinywe
R63 – Ingozi engaba khona yokulimala enganeni engakazalwa
R36/37/38 – Ukucasula amehlo, uhlelo lokuphefumula kanye nesikhumba.
I-R11 – Ivutha Kakhulu
R67 – Izihwamuko zingadala ukozela kanye nesiyezi
R65 – Iyingozi: Ingadala umonakalo wamaphaphu uma igwinyisiwe
R48/20 -
Incazelo Yokuphepha S53 – Gwema ukuchayeka – thola imiyalelo ekhethekile ngaphambi kokuyisebenzisa.
S16 – Zigcine kude nemithombo yokuthungela.
S36/37/39 – Gqoka izingubo zokuzivikela ezifanele, amagilavu ​​kanye nokuvikela iso/ubuso.
S45 – Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.)
I-S37/39 – Gqoka amagilavu ​​afanelekile kanye nokuvikela iso/ubuso
I-S28A -
S26 – Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha.
I-S62 – Uma igwinyisiwe, ungabangeli ukuhlanza; funa iseluleko sezokwelapha ngokushesha futhi ubonise lesi sitsha noma ilebula.
I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
Ama-ID e-UN UN 2345 3/PG 2
I-WGK Germany 3
I-RTECS UK4375000
AMAKHODI E-FLUKA BRAND F 8
I-TSCA Yebo
Ikhodi ye-HS 29033990
Inothi Lengozi Ivutha Kakhulu/Inobuthi/Iyagqwala
I-Hazard Class 3
Iqembu Lokupakisha II

 

Isingeniso

I-3-Bromopropyne, eyaziwa nangokuthi i-1-bromo-2-propyne, iyinhlanganisela yezinto eziphilayo. Okulandelayo isingeniso esifushane sezakhiwo zayo, ukusetshenziswa kwayo, izindlela zokukhiqiza kanye nolwazi lokuphepha:

 

Ikhwalithi:

- Inomthamo ophansi, onenani elicishe libe ngu-1.31 g/mL.

I-3-Bropropyne inephunga elimnandi.

- Ingancibilika kwezinye izincibilikisi eziphilayo njenge-ethanol ne-ether.

 

Sebenzisa:

- I-3-Broproyne isetshenziswa kakhulu njenge-reagent ekuphenduleni kwe-organic synthesis, isibonelo ingabamba iqhaza ekuphenduleni kwe-metal-catalyzed cross-coupling for synthesis of organic compounds.

- Ingasetshenziswa futhi njengesiqalo sama-alkynes, isb ekuhlanganiseni ama-alkynes noma amanye ama-alkynes asebenzayo.

 

Indlela:

- I-3-Bromopropyne ingatholwa ngokusabela kwe-bromoacetylene ne-ethyl chloride ngaphansi kwezimo ze-alkali.

- Lokhu kwenziwa ngokuxuba i-bromoacetylene ne-ethyl chloride bese wengeza inani elithile le-alkali (njenge-sodium carbonate noma i-sodium bicarbonate).

- Ekupheleni kokusabela, i-3-bromopropynne ehlanzekile itholakala ngokuxutshwa nokuhlanzwa.

 

Ulwazi Lokuphepha:

- I-3-Bropropyne iwubuthi futhi iyacika edinga ukuthi kugqokwe okokusebenza okufanele kokuzivikela komuntu (i-PPE) uma usebenza.

- Kufanele igweme ukuthintana nama-oxidants, ama-alkali aqinile, nama-acids aqinile ukuze kugwenywe ukusabela okuyingozi.

- Ukuthobela izinqubo zokusebenza zokuphepha ezifanele ngesikhathi sokusetshenziswa nokugcinwa.

- Uma ubamba i-3-bromopropyne, qinisekisa ukuthi umoya ungena kahle futhi ugweme ukuhogela umhwamuko wayo noma ukuthintana nesikhumba namehlo.

 


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