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umkhiqizo

I-salicylaldehyde(CAS#90-02-8)

Isakhiwo Samakhemikhali:

I-Molecular Formula I-C7H6O2
I-Molar Mass 122.12
Ukuminyana 1.146 g/mL ku-25 °C (lit.)
I-Melting Point 1-2 °C (okhanyisiwe)
I-Boling Point 197 °C (okhanyisiwe)
I-Flash Point 170°F
Inombolo ye-JECFA 897
Ukuncibilika kwamanzi encibilikayo kancane
Ukuncibilika 4.9g/l
I-Vapor Presure 1 mm Hg ( 33 °C)
I-Vapor Density 4.2 (vs air)
Ukubukeka Uketshezi
Umbala Okuphuzi okucacile
Iphunga Ama-alimondi ababayo
Umkhawulo Wokuchayeka ACGIH: TWA 5 ppm (Isikhumba)OSHA: TWA 5 ppm(19 mg/m3)NIOSH: IDLH 250 ppm; TWA 5 ppm(19 mg/m3); Isilingi 15.6 ppm(60 mg/m3)
I-Merck 14,8326
I-BRN 471388
pKa 8.37(ku-25℃)
PH 6-8 (H2O, 20℃)Ayisebenzi
Isimo Sesitoreji -20°C
Ukuzinza Izinzile. Okuvuthayo. Akuhambisani nezisekelo eziqinile, ama-ejenti anciphisa amandla, ama-acids aqinile, ama-oxidizing aqinile.
Kuyazwela Kuyazwela Umoya Nokukhanya
I-Refractive Index n20/D 1.573(lit.)
Izakhiwo Zomzimba Nezamakhemikhali Uketshezi olungenambala, olucacile, olunamafutha, olunephunga elishisayo nephunga le-alimondi; Umfutho we-vapor:.13kPa/33 ℃; Iphuzu elikhanyayo: 76 ℃; Iphuzu lokuncibilika -7 ℃; Iphuzu lokubilisa 197 ℃; Ukuncibilika kuncibilika kancane emanzini, kuncibilika ku-ethanol, ether; Ukuminyana: Ukuminyana okuhlobene (amanzi = 1)1.17; ukuzinza: Izinzile
Sebenzisa Ukusetshenziswa okuyinhloko: esetshenziswa njengama-reagents okuhlaziya, izinongo, izithasiselo zikaphethiloli kanye ne-organic synthesis

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi R21/22 – Kuyingozi ukuthinta isikhumba futhi uma ugwinyiwe.
R36/38 – Ukucasuka emehlweni nasesikhunjeni.
I-R68 – Ingozi engaba khona yemiphumela engenakuhlehliswa
R36/37/38 – Ukucasula amehlo, uhlelo lokuphefumula kanye nesikhumba.
R20/21/22 – Kuyingozi ngokuhogela umoya, ukuthintana nesikhumba futhi uma ukugwinyile.
R51 – Kunobuthi ezintweni eziphila emanzini
R36 – Ukucasuka emehlweni
R51/53 – Ukuba nobuthi ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini.
I-R22 – Iyingozi uma igwinywe
Incazelo Yokuphepha S26 – Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha.
I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
S36/37/39 – Gqoka izingubo zokuzivikela ezifanele, amagilavu ​​kanye nokuvikela iso/ubuso.
S36 – Gqoka izingubo ezifanele zokuzivikela.
I-S61 - Gwema ukudedelwa endaweni. Bheka imiyalelo ekhethekile / amaphepha edatha okuphepha.
I-S64 -
S29/35 -
Ama-ID e-UN 3082
I-WGK Germany 2
I-RTECS VN5250000
AMAKHODI E-FLUKA BRAND F 8-10-23
I-TSCA Yebo
Ikhodi ye-HS 29122990
I-Hazard Class 6.1(b)
Iqembu Lokupakisha II
Ubuthi I-MLD kumagundane (mg/kg): 900-1000 sc (Binet)

 

Isingeniso

I-salicylaldehyde iyinhlanganisela yezinto eziphilayo. Okulandelayo yisingeniso sezakhiwo, ukusetshenziswa, izindlela zokulungiselela kanye nemininingwane yokuphepha ye-salicylaldehyde:

 

Ikhwalithi:

- Ukubukeka: I-salicylaldehyde iwuketshezi olungenambala ukuya kokuphuzi olunephunga elikhethekile le-alimondi elibabayo.

- Ukunyibilika: I-salicylaldehyde inokunyibilika okuphezulu emanzini futhi iphinde incibilike kuzincibilikisi eziningi zemvelo.

 

Sebenzisa:

- Ama-flavour nama-flavour: I-salicylaldehyde inephunga elimnandi le-alimondi elibabayo elihlukile futhi ijwayele ukusetshenziswa kumakha, izinsipho nogwayi njengenye yezingxenye zephunga.

 

Indlela:

- Ngokuvamile, i-salicylaldehyde ingakhiqizwa ku-salicylic acid ngokusabela kwe-redox. I-oxidant esetshenziswa kakhulu yisisombululo esine-acidic potassium permanganate.

- Enye indlela yokulungiselela ukuthola i-salicylyl alcohol ester nge-chlorination ester ye-phenol ne-chloroform eyenziwe nge-hydrochloric acid, bese uthola i-salicylyldehyde nge-hydrolysis reaction catalyzed by acid.

 

Ulwazi Lokuphepha:

- I-salicylaldehyde iyikhemikhali enokhahlo futhi kufanele igwenywe ukuthintana ngqo nesikhumba namehlo.

- Uma usebenzisa noma uphethe i-salicylaldehyde, gcina izimo ezinhle zokungenisa umoya futhi ugweme ukuhogela umhwamuko wayo.

- Lapho ugcina i-salicylaldehyde, kufanele igcinwe esitsheni esingangeni moya, kude nokuvutha kanye nama-oxidants.

- Uma i-salicylaldehyde idliwe noma ihogelwe ngephutha, funa usizo lwezokwelapha ngokushesha.


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