I-sodium borohydride(CAS#16940-66-2)
Amakhodi Engozi | I-R60 - Ingase iphazamise inzalo U-R61 - Ingabangela ukulimala enganeni engakazalwa R15 – Ukuthintana namanzi kukhulula amagesi avuthayo kakhulu R34 – Ibangela ukusha R23/24/25 – Kunobuthi ngokuhogela, ukuthintana nesikhumba futhi uma ugwinywe. R24/25 - R35 – Idala ukusha kanzima R21/22 – Kuyingozi ukuthinta isikhumba futhi uma ugwinyiwe. R51/53 – Ukuba nobuthi ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini. R42/43 - Ingabangela ukuzwela ngokuhogela umoya nangokuthinta isikhumba. R49 – Ingabangela umdlavuza ngokuhogela R63 – Ingozi engaba khona yokulimala enganeni engakazalwa R62 – Ingozi engaba khona yokukhubazeka kokuzala R36/38 – Ukucasuka emehlweni nasesikhunjeni. R43 - Ingabangela ukuzwela ngokuthinta isikhumba I-R19 – Ingase yenze ama-peroxides aqhumayo I-R68 – Ingozi engaba khona yemiphumela engenakuhlehliswa R50/53 – Kunobuthi kakhulu ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini. |
Incazelo Yokuphepha | S53 – Gwema ukuchayeka – thola imiyalelo ekhethekile ngaphambi kokuyisebenzisa. S43 – Uma kusetshenziswa umlilo … (kulandela uhlobo lwempahla yokucisha umlilo ezosetshenziswa.) S45 – Uma kwenzeka ingozi noma uzizwa ungaphilile, funa iseluleko sezokwelapha ngokushesha (bonisa ilebula noma nini lapho kunokwenzeka.) I-S43A - S36/37/39 – Gqoka izingubo zokuzivikela ezifanele, amagilavu kanye nokuvikela iso/ubuso. S26 – Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha. S22 - Ungaphefumuli uthuli. I-S50 - Ungaxubani ne... I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu. I-S61 - Gwema ukudedelwa endaweni. Bheka imiyalelo ekhethekile / amaphepha edatha okuphepha. |
Ama-ID e-UN | UN 3129 4.3/PG 3 |
I-WGK Germany | 2 |
I-RTECS | ED3325000 |
AMAKHODI E-FLUKA BRAND F | 10-21 |
I-TSCA | Yebo |
Ikhodi ye-HS | 28500090 |
I-Hazard Class | 4.3 |
Iqembu Lokupakisha | I |
Ubuthi | I-LD50 ngomlomo kuNogwaja: 160 mg/kg LD50 dermal Rabbit 230 mg/kg |
Isingeniso
I-sodium borohydride iyinhlanganisela ye-inorganic. Kuyimpushana eqinile encibilika kalula emanzini futhi ikhiqize isixazululo se-alkaline.
I-sodium borohydride inamandla okunciphisa izakhiwo futhi ingasabela ngezinhlanganisela eziningi eziphilayo. Isetshenziswa kabanzi ku-organic synthesis futhi ivame ukusetshenziswa njenge-agent ye-hydrogenating. I-sodium borohydride inganciphisa ama-aldehyde, ama-ketone, ama-ester, njll. kuma-alcohols ahambisanayo, futhi inganciphisa nama-acids abe otshwala. I-sodium borohydride ingasetshenziswa futhi ku-decarboxylation, dehalogenation, denitrification nokunye ukusabela.
Ukulungiswa kwe-sodium borohydride ngokuvamile kutholakala ngokusabela kwe-borane nensimbi ye-sodium. Okokuqala, insimbi ye-sodium isabela nge-hydrogen ukuze kulungiswe i-sodium hydride, bese isabela nge-trimethylamine borane (noma i-triethylaminoborane) ku-ether solvent ukuze kutholwe i-sodium borohydride.
I-sodium borohydride iyi-ejenti yokunciphisa enamandla esabela ngokushesha enomswakama nomoya-mpilo emoyeni ukuze ikhulule i-hydrogen. Isitsha kufanele sivalwe ngokushesha futhi sigcinwe somile ngesikhathi sokusebenza. I-sodium borohydride iphinde ihlangane kalula nama-asidi ukuze ikhulule igesi ye-hydrogen, futhi ukuthintana nama-asidi kufanele kugwenywe. I-sodium borohydride nayo inobuthi, futhi kufanele kuqashelwe ukugwema ukuhogela noma ukuthinta isikhumba. Uma usebenzisa i-sodium borohydride, gqoka amagilavu okuzivikela kanye nezibuko, futhi uqinisekise ukuthi ukuhlinzwa kwenziwa endaweni enomoya omuhle.