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umkhiqizo

I-Triphenylphosphine(CAS#603-35-0)

Isakhiwo Samakhemikhali:

I-Molecular Formula I-C18H15P
I-Molar Mass 262.29
Ukuminyana 1.132
I-Melting Point 79-81°C(lit.)
I-Boling Point 377°C(okhanyisiwe)
I-Flash Point 181 °C
Ukuncibilika kwamanzi Ayincibiliki
Ukuncibilika amanzi: ancibilikayo0.00017 g/L ku-22°C
I-Vapor Presure 5 mm Hg ( 20 °C)
I-Vapor Density 9 (vs emoyeni)
Ukubukeka Amakristalu, i-Crystalline Powder noma ama-Flakes
I-Gravity ethize 1.132
Umbala Emhlophe
I-Merck 14,9743
I-BRN 610776
Isimo Sesitoreji Gcina ngaphansi kuka +30°C.
Ukuzinza Izinzile. Akuhambisani nama-oxidizing agents, ama-acids.
Kuyazwela I-8: isabela ngokushesha ngomswakama, amanzi, izincibilikisi ze-protic
I-Refractive Index 1.6358
Izakhiwo Zomzimba Nezamakhemikhali Ukuminyana 1.132
iphoyinti lokuncibilika 78.5-81.5°C
iphoyinti abilayo 377°C
iphoyinti elikhanyayo 181°C
Amanzi angancibiliki
Sebenzisa Isetshenziswa ku-organic synthesis, ebuye isetshenziswe njenge-polymerization Initiator, i-antibiotic drug clindamycin nezinye izinto zokusetshenziswa.

Imininingwane Yomkhiqizo

Omaka bomkhiqizo

Amakhodi Engozi I-R22 – Iyingozi uma igwinywe
R43 - Ingabangela ukuzwela ngokuthinta isikhumba
R53 – Ingabangela imiphumela emibi yesikhathi eside endaweni yasemanzini
R50/53 – Kunobuthi kakhulu ezintweni eziphila emanzini, kungabangela imiphumela emibi yesikhathi eside endaweni yasemanzini.
R48/20/22 -
Incazelo Yokuphepha I-S36/37 – Gqoka izingubo zokuzivikela ezifanele namagilavu.
S60 – Le nto kanye nesiqukathi sayo kumele kulahlwe njengemfucuza eyingozi.
I-S61 - Gwema ukudedelwa endaweni. Bheka imiyalelo ekhethekile / amaphepha edatha okuphepha.
S36/37/39 – Gqoka izingubo zokuzivikela ezifanele, amagilavu ​​kanye nokuvikela iso/ubuso.
S26 – Uma uthintana namehlo, geza ngokushesha ngamanzi amaningi futhi ufune iseluleko sezokwelapha.
Ama-ID e-UN 3077
I-WGK Germany 2
I-RTECS SZ3500000
AMAKHODI E-FLUKA BRAND F 9
I-TSCA Yebo
Ikhodi ye-HS 29310095
Ubuthi I-LD50 ngomlomo kuNogwaja: 700 mg/kg LD50 dermal Unogwaja > 4000 mg/kg

 

Isingeniso

I-Triphenylphosphine iyinhlanganisela ye-organophosphorus. Okulandelayo yisingeniso sezakhiwo, ukusetshenziswa, izindlela zokulungiselela kanye nolwazi lokuphepha lwe-triphenylphosphine:

 

Ikhwalithi:

1. Ukubukeka: I-Triphenylphosphine iyikristale emhlophe ukuya kokuphuzi noma okuqinile okuyimpuphu.

2. Ukunyibilika: Incibilika kahle kuzincibilikisi ezingezona ze-polar njenge-benzene ne-ether, kodwa ayincibiliki emanzini.

3. Ukuzinza: I-Triphenylphosphine izinzile uma kuqhathaniswa nezinga lokushisa legumbi, kodwa izokhipha i-oxidize ngaphansi kwethonya lomoya-mpilo kanye nomswakama emoyeni.

 

Sebenzisa:

1. I-Ligand: I-Triphenylphosphine iyi-ligand ebalulekile ekuhlanganiseni kwamakhemikhali. Yakha ama-complexes anezinsimbi futhi isetshenziswa kakhulu ku-organic synthesis kanye nokusabela kwe-catalytic.

2. I-ejenti yokunciphisa: I-Triphenylphosphine ingasetshenziswa njenge-ejenti yokunciphisa ephumelelayo yokunciphisa ama-carbonyl compounds ezinhlobonhlobo zokusabela kwamakhemikhali.

3. Ama-Catalysts: I-Triphenylphosphine kanye nokuphuma kwayo kuvame ukusetshenziswa njengama-ligand we-transition metal catalysts futhi ibambe iqhaza ekuphenduleni kwe-organic synthesis.

 

Indlela:

I-Triphenylphosphine ivame ukulungiswa ngokusabela kwe-hydrogenated triphenylphosphonyl noma i-triphenylphosphine chloride nge-sodium metal (noma i-lithium).

 

Ulwazi Lokuphepha: Izinto zokuzivikela ezifanele ezifana namagilavu ​​nezibuko kufanele zigqokwe.

2. Gwema ukuthintana nama-oxidants nama-asidi aqinile, okungase kubangele ukusabela okuyingozi.

3. Kufanele igcinwe endaweni eyomile, engenawo umoya, kude nezinto ezingahambelani nemithombo yomlilo.

 


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